One of youre Pokemon needs to have the move headbutt then talk to a tree the one's that look like christmass trees and you'll have to do in the afternoon then just shake the trees a couple of times with headbutt and you will begin a fight against caterpie or if youre lucky pineco
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Pineco is quite rare and even if you do see one and it escapes you cannot look on the pokedex to see where it might appear....headbutting trees is your only hope of finding one (unless you have a game shark) but to improve the chances of finding one if you headbutt trees in between 3:30 and 4 in the afternoon, then you probably will come across one... try headbutting trees on route 39 (that's where i found mine)
Goodluck
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Outside of Mt.Silver.
he evolves at lev.31
teach headbut to a Pokemon (anyone can learn it), then headbut the tree on route 31 that is by itself. pineco will then appear around lv 4.
After national dex you find it at altering cave its Levels: 20 +
If you mean where do i catch a pineco in fire red, go to pattern bush i think.