Kangaskhan is found exclusively in the Safari Zone. When it appears, try throwing some bait then hit it with a stone. Do this for 3 times. If the Pokemon didn't run, try throwing a Safari ball and you will have a high chance to catch it. Remember not to throw 2 rocks consecutively cos it will run.
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In Rock Tunnel
It is in Rock Tunnel.
Kangaskhan can be found rarely in the Safari Zone north of Fuschia City.
you find kangaskhan in area 2 of the safari zone in Pokemon leaf Green ... not sure in fire red sorry
you need to find it in the safari zone in area1.