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use 3 seakings with aqua ring or water fall and you are done
He will appear after you beat the 7th gym leader.
the fire gym is in cinnabar island
Blue (The eighth gym leader) is waiting on Cinnabar. He won't battle you unless you've beat the rest of the gym leaders
The Cinnabar gym key is in the abandoned mansion west of the gym. Spray on a super repel and get to work!