It's shown in the TV series that they keep their Poke balls on their belts, tucked in. Some keep them in purses, but most have the special belts with 6 loops to secure their pokeballs.
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Pokéballs are the containers that pokémon are stored in. Just search "pokémon" in wikipedia for more info. This is by conditions : Pokeballs are little ball that keep your Pokemon in it . It is like a Pokemon house.
Every time you buy ten pokeballs, you get a premier ball, so if you buy ten pokeballs at a time and then sell them all back, you'll keep getting premier balls and you'll basically save a crapload of pokepoints (money in pokemon)
Yes trainers can rematch you in Pokemon crystal but you must register there phone numbers to do that but not all trainers will rematch you, wait until the trainers call you they will mention they want to battle again and they will remind you where they are go there and talk to the trainer to battle them again. They can keep calling you for rematches throughout the game don't miss the chance to rematch them.
At any random time..actually..keep calling them in ur pokenav!
Every Pokemon can reach level 100 to get your Pokemon to level 100 takes time and a lot of determination. My advice is to go to seven island and defeat the trainers in sevault canyon that are near a house when your Pokemon are weak go in the house talk to the guy to get your Pokemon healed! Keep defeating trainers and healing your Pokemon and sooner or later your Pokemon will reach level 100.