get the TM and teach it to it
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Tm Iron Tail is near the village bridge but u have to use the dowsing machine in order to find it
You can't teach Scyther any steel type moves, you have to evolve it by trading it while it is holding the metal coat. When it evolves into Scizor, that is when it can learn steel moves. It learns metal claw at level 21, iron defense at level 37, and iron head at level 53.
pikachu doesnt learn iron tail.u must teach it with the TM
There are many ways to increase the friendship of your Pokemon. You can walk around A LOT with the Pokemon (I think that is the slowest method), you can battle with that Pokemon, you can give the Pokemon things such as Iron, Protein, Carbos, Calcium, etc., and letting the Pokemon hold the soothe bell also helps with these things. Hope this helps!
It increases your Pokemon's defense.