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The move Double Edge isn't available as a TM in Pokemon Leafgreen. Instead, head to the very end of Victory Road and talk to the person near the exit - he will tell you that you've worked very hard and you deserve to have one of your Pokemon learn Double Edge. It works just like a TM, but you can't carry it around with you - it's an in-game thing.

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Q: How can you get the TM Double Edge in Pokemon Leaf Green?
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