To be Piplup in PMD2, you need to get either an impish nature (male) or a quirky nature (female) as a result when you take the personality test.
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Piplup is only found in Pokemon Mystery Dungeon Explorers of Time and Darkness. It is one of the Pokemon that you can become in the beginging. If you don't get Piplup, it can be found in Crevice Cave(floors 1-10.)
On Pokemon Mystery Dungeon: Explorers of Time/Darkness, you take a survey at the beginning of the game. The answers you chose will determine what Pokemon you are most like, and you will be that Pokemon.
You trade one from Platinum, Pearl, Diamond, Ranger or Mystery Dungeon. From Eatmycheeseballs.com
Piplup is a starter Pokemon in Pokemon Pearl. you can get him early in the game as your starter Pokemon.
Choose it as your Starter Pokemon.