You can't catch a wild butterfree in Pokémon fire red. You have to catch either a Caterpie or Metapod and evolve them. Caterpie evolves at level 7 and Metapod evolves at level 10. Have fun! :)
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butterfree and venonat
You have to trade from Firered, Leafgreen or Pokemon XD.
You cannot catch a Butterfree, so to get one, you will have to evolve a metapod
You can catch a caterpie or metapod at the national park north of goldenrod city. After you catch the caterpie evolve it to a Metapod and then evolve it to a Butterfree.
To get Pokemon firered on PC download a vba and Pokemon firered ROM