Go to a Heart Scale move Tutor and give him a heart scale. In Emerald he's in the house beside the Battle Tent. In HG/SS, he's the guy standing closest to the table, in the house in the south-west corner of BlachThorn City. And in Platinum, he's in the house right beside a large body of water, on the south east side of Pastoria City.
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Aipom doesn't learn double hit in emerald, ruby, or sapphire
unfortunately aipom doesn't learn double hit at all in emerald,sapphire or ruby
Have it learn Double Hit, then level it up.
Aipom will evolve into ambipom when leveled up while knowing the move Double Hit. Aipom learn Double Hit at level 32, so the earliest level it can be evolved into an ambipom is level 33.
at level 32, only because it learns double-hit. if you don't let aipom learn this move. it won't evolve.