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No. The Yu-gi-oh card maker is just for fun, and not officially affiliated with Konami (the company that owns Yu-gi-oh). You can just make cards that look like it but you can not actually print it like a real yu-gi-oh card.
There are many fake cards produced by counterfeiters trying to profit from Yu-Gi-Oh. Most fakes are based on a real card, but there's a fake card called 'Darkly Big Rabbi' that's based on a complete version of Exodia but is not based on any legitimate card.
In Yu-Gi-Oh World Championships 2008, and probably all the other Yu-Gi-Oh games, Select the card with the keypad as though you were going to move it from the deck to the trunk, and you will see an option with a card and sparkle, activate it and it will be set as your key card.
Zorc Necrophades, the main villain in the "Dawn of the Duel" arc in the Yu-Gi-Oh! anime, has not been made into an offical Yu-Gi-Oh! card.However, Dark Master - Zorc, based on the Zorc in Yu-Gi-Oh! "season zero", is a legitimate card.
Mystical Guillotine is not a real Yu-Gi-Oh! card it is an anime-exclusive card; however, it does share its art with the OCG-version of Tragedy.