Startle and stun are synonyms for astonish. They begin with the letters ST.
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The longest word starting with E is Electroencephalographically.
A four letter word starting with the letter a is able.
A seven letter word starting with E could be epitome.
Waterhose is a nine letter word starting with the letter W!
Floccinaucinihilipilification is the longest word starting with F; it means the act of estimating something as worthless.