You cannot get Aipom in Leaf Green, but you can get it in the Safari Zone in Emerald
--- The answer on the top is wrong, you can get it in leaf green in altering cave ----
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Aipom is not available in leafgreen have Emerald or Pokemon Colosseum trade you one.
You can obtain an Aipom by headbutting trees.
It doesn't evolve in leaf green
aipom's evole is a Pokemon from the next generation after emerald so its impossible to receive him.
aipom does not evolve inpokemon emerald