A five letter word, second letter F is after or often.
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freer
hefty
A five (5) letter word that starts with Z and ends with F, there is none recorded. However, there is a word that starts with Z and ends with F. The word is a four (4) letter word: zarf, (noun) a metal holder for a coffee cup.
fuzzy
There's no such word much less a TV show that has M as the first letter & F as the second letter.