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The shield materia can only be found in the northern cave. You have to enter the northern cave on disc 3 and climb down until the point where you have to choose a direction to go. To get shield, take the left path, then you will have to decide on a direction again i can't remember whether you go up or down but if you choose the right path you should end up in some slimy place which looks a bit like someone's insides. Go to the next room and there you should see a green blob on one of the slimy bits this is the shield materia. Hope I helped =)

If you don't find this helpful try this:

http://www.eyesonff.com/ff7/walkthru3.php

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13y ago

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Q: FF7 ps1 how to get SHIELD materia?
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