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Arceus, Bibarel, Floatzel, and Mew are four Pokemon that can learn at least four different HMs.
make your floatzel learn icebeam by TM but level it up first because her garchomp has giga impact.
most water Pokemon
Gyarados cannot learn Dive by itself from leveling and must learn it from the HM Dive which is not available in Pokemon Platinum. The HM for Dive is only available in Pokemon versions; Ruby, Sapphire, Emerald, White, Black, White2, and Black2
Floatzel cannot learn Hydro Pump.