A Moonstone does not trigger a Pikachu's evolution. Pikachu evolves from its baby evolution (Pichu) through friendship/happiness. It cannot evolve into its final evolution, Raichu, without a Thunderstone. It will never evolve upon levelling up even if it has max friendship/happiness with its trainer.
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get a moonstone. get a Pokemon that can evolve with a moonstone. go to your bag. choose the moonstone. choose use. select your Pokemon. Congrats on your new Pokemon
skitty does not evolve by level. it evolve's by giving it a moon stone and you will have a delcatty.If you give your Skitty a moonstone, it will evolve.Use a moonstone!
Moonstone makes pokemon evolve.
Pikachu do not evolve by level. They evolve when a thunderstone is used on them.
Pikachu will evolve into Raichu when given a thunder stone. If you mean Ash's Pikachu, then it very unlikely he will evolve his Pikachu, as Pikachu is the Pokemon Franchise's mascot.