All I remember is that he caught a shiny noctowl, if you consider that rare Ash also catches Snorlax
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Yes threre is a way, you can catch a couple of meowths and they might pick up rare candies. You can also trade to Emerald and copy them.
No. How can you catch a Pokemon if you cant weaken it. In Pokemon ranger though you can capture your partner Pokemon.
there is not any combo
Not any hoenn Pokemon but firered and leafgreen can catch alot of kanto and johto Pokemon ruby and sapphire can and can't.
You can not catch any of them in black or white, but I think that you can catch all 3 in diamond.