yes near vermillion city there is a camper near a lass or camper girl he has a squirtle.
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You get Squirtle as one of the starter pokemon.
Gary(or what ever name u put him) has one when hes the champion and if u started with squirtle and if you go to the trainer tower there is a trainer who has a venusaur lv.78(in the knockout competion plus hes kinda near the end
Trade them from firered or leafgreen.
your rival in the game
Pokemon Trainer uses Ivysaur, Charizard and Squirtle.