Yes, Vullaby does evolve in Pokémon White, it will evolve into Mandibuzz at level 54.
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Vullaby does not evolve with a stone. It evolves when it reaches level 54.
Vullaby
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Vullaby evolves starting at level 54 into Mandibuzz.
Cynthia has a Mandibuzz in White version. And for Black version she has a Braviary.