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I don't know where regiice is but you find regirock once you've defeated Cynthia twice and registeel in iron island when you get the national pokedex.
the kanto pokedex YES national not sure but i think you have to trade from ruby or sapphire or something
You need to get 100 pokemon then go and talk to professor Birch and he will upgrade your pokedex.
complete pokedex and catch the rest of the legendairies witch are regirock regice registeel ho-oh and lugia
You can't catch a Pineco in Saphire if you don't have the National Pokedex. Otherwise, you will have to trade for one.