Yes, after getting their phone number
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You cannot rebattle Gym Leader in Pokemon White.
you can only rebattle gym leaders when you have defeated the elite four, check your match call on the pokenav when you have
This is also what im finding but im not sure. I have the code for trainer rebattle but not gym leader rebattle. Well im sure i have seen "Press R to Rebattle Gym Leader"
You cannot rebattle Gym Leaders.
you battle trainers again by adding them onto your pokegear and then soon they will want a rematch