the only way to jump on bike is to jump of a cliff!
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The eterna city bike shop.
The bike shop is in Eterna City.
Get an Acro Bike and hold down B while moving.
Go to Mauville city and get the acro bike then pess the b or a(i dont know which)button near the bike bridge to make it jump!
He is in Eterna City, to the south of the Pokemon Center.