No but you can catch many of the Pokemon in Sinnoh after you beat the Elite 4
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u cant go to the kanto but u can get kanto Pokemon in 2 ways.1 u can look 4 them.2 if the game boy trader thing you cood trade Pokemon.
You don't. The only way to get Charizard on Pokemon Pearl is to migrate one from the Kanto Reigion.
First you have to defeat the pokemon league and go to Kanto. In Kanto you have to go to Oak's lab and he will offer you one of the three starter pokemon for Kanto.
Yes! it is sortof difficult (you need to get a 1000 win streak at the battle tower to go yo hoenn, 2000 to go to kanto and 3500 to go to johto) but it works. And I don't think you can go to Unova, but at least you can go to hoenn johto and Kanto!
I believe that you can get to Kanto after defeating the Pokemon league and getting the National Pokedex.