Yes, you can get the moon ball in Pokemon Black and White, but you have to have an Action Replay Dsi to get it.
It isn't like a normal pokeball, you can't catch any pokemon with it, the ball is just an item.
List of non-pokeballs:
Fast Ball
Level Ball
Lure Ball
Heavy Ball
Love Ball
Friend Ball
Moon Ball
Sport Ball
Park Ball
These are just items, not real pokeballs, so dont expect them to catch any pokemon.
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Moon Stone!
The only Pokemon from Black/White you can evolve with a moon stone is Munna to Musharna.Otherwise, you can use a moonstone to evolve these Pokemon from previous generations while they are in Pokemon Black/White.Nidorina -> NidoqueenNidorino -> NidokingClefairy -> ClefableJigglypuff -> WigglytuffSkitty -> Delcatty
in Pokemon black munna evolves using the moon stone but be careful because it wont learn any moves after you evolve it
Moon Stone.
you can get one from lenora when you get the dragon skull back