No. You can only pick Turtwig, Chimchar, or Piplup. If you want starters from a different region, there might be an action replay code for it.
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By trading the other starters with other players of Diamond or Pearl.
in Pokemon pearl you can get any starter by the gts if you want charzard i can give you one
No you cannot go to other regions in Pokemon Pearl or Diamond version but in Pokemon Heart Gold and Soul Silver you can go to the Jotoh region.
Pokemon sapphire for starters but on the main Pokemon Diamond and pearl Pokemon Mystery Dungeon Explorers of Sky is.
Unfortunantly you cant go to other regions in Pokemon diamond and pearl. its not like leafgreen,firered,gold,silver and crystal version where you travel to different regions. You can't, Sinnoh is the only region available in the game.