No, Palkia is totally not available in emerald. Only in Diamond Pearl and Platinum I think
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because palkia and dialga weren't around that early of pokemon emerald. they are newer then emerald
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You can't get Dialga and Palkia in Emerald.
arceus,dialga,palkia,rayquaza,groudon,and kyogre ha ha just kidding
You can get Palkia in Pearl, otherwise you have to transfer Palkia from Pokemon Pearl to Pokemon Diamond.