Yes I believe there is actually a trainer on Route 212 who has a Monferno on route 212 the Pokemon rainger double bttle have one
p.s. go down from hearthome. right when you walk south and it starts raining the double rangers are the first ones youll see. :D also if you never seen a leafeon and a marill they will be the other trainers Pokemon. the trainer with monferno only has monferno.
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On route 215 there are two trainers, Dennis and Maya. During the double battle, Dennis will send out a Monferno. Also if you started off with a Turtwig, your rival will have a Monferno in his party
There is no wild Monferno.You can only get Monferno by picking Chimchar as your starter and evolving it.
Lucas has a Monferno.
You either choose a monferno for your starter. Or if you choose a turtwig as your starter your rival will have monferno.And you can find it in south on route 212 and ranger jeffery will have it. That is all the way you can see monferno in pokemon platinum.
you can find the trainer with the misdreavus in platinum in hearthome city i believe