if you act fast you can catch shamin now off of the mystery gift option it ends soon (oct 14today)you will get oaks letter and it will tell you the rest. shamin is at level 30 save right as u see him and if you have money by a quick ball use it on the first turn.he is easy to catch hint if you want sky form talk to the blond girl in floroma town with shamin on your team.giveshakin those flowers
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You ether go to a Nintendo event or you can use a AR code where there's a a hidden area in the south of Victory Road guaded by some man
You need to activate the event that will deliver Oak's letter to the guy in the Pokemart. (By either action replay or going to an event) then after receiving it go to victory road and find the exit that leads to route 224 from there go north to the white rock where you'll meet Prof. Oak the rock will move and a long path will appear, follow it and at the end (it's long, very, very long.) and you will see Shaymin. All you need to do is go up and interact with it like any other legendary Pokemon. It's at level 30 so bring a Pokemon that level or one with the move "False Swipe" witch leaves one Hp left.