You can catch any Pokemon with any ball it all depends on luck.
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you can use master ball in caught the groudon
by holding r+l bumpers and rapidly tapping a weaken it...................
I would use a dusk ball.
Yes, the Ultra Ball has a 4x catch rate than a Premier Ball, which has the same catch rate as a normal Poke Ball. It is commonly used to catch rare or Legendary Pokemon.
you just need to get the master ball off the galactic grunt boss it has a 100% catch rate hope i helped or you can buy lots of ultra then go to terra cave (thats where find and weaken groudon down real low like about its about to faint but dont kill it then try to catch groudon with an ultra ball this will take patience.........lots of patience