yes you can by putting a male and female pikachu in the daycare together
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Breed two pikachu or raichu of opposite gender in the daycare which is below goldenrod city.
You have to catch two pikachu. Make sure they are opposite genders. Then you put them both in the day care center at Goldenrod City, and they will breed and create a pichu. Also you can breed any Pokemon with a Ditto including pikachu
If you breed a gold and silver chao, you can get * a Gold chao * a Silver chao * a Gold chao with silver highlights * Or a Silver chao with gold highlights If you didn't get any of these, somethings wrong with your gamecube/dreamcast
Everything except for legendaries and another ditto. In Pokemon Gold and Silver, you could breed two dittos.
cerulean cave after you beat all the gym leaders