Magnemite cannot breed unless it has evolved to Magneton or Magnezone.
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You can get a magnemite in New Mauville.
Magnemite evolves into Magneton starting at level 30.
Magnemite evolves into Magneton on level 30.
In Fire Red Magnemite is at the Power Plant.
In Pokemon Diamond and Pearl you need the National Pokedex to get Magnemite. In Pokemon Platinum you don't need the National Pokedex to get Magnemite.