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Zambia and Zimbabwe.
There are 2 countries in Africa that begin with the letter Z. The countries are Zambia and Zimbabwe.
Zambia and Zimbabwe both start with the letter 'z'.
The highest waterfall in Africa is the Tegula Falls at 948 metres, which are in South Africa. A waterfall near a country beginning with Z is the Victoria Falls on the river Zambezi, which lie between the countries of Zimbabwe and Zambia.
Zambia and Zimbabwe are the only countries that begin with the letter z. Cities that begin with the letter z include Zurich Switzerland, Zagreb Croatia and Zanesville Ohio.