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The VOL(ume) can mean either two things.

1. If it's a percentage i.e 12% it means that the actual alcohol content out of 100% is 12 etc. The extra stuff will be, water, yeast, hops, grapes, flavouring, sugar depending on the drink.

2. The volume could simply by the amount of liquid-i.e a litre, 75cl(3/4 of a litre) or 750ml-often on wine bottles.

But 'vol' is the abbreviation of the word volume essentially.

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Q: What does vol on alcohol bottles stand for?
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