A cup it 8 ounces. A stick of butter is 4 ounces, or half a cup. Two thirds of a cup would be roughly 5.3 ounces, so you would need approximately one and a third sticks of butter to equal 2/3rds of a cup.
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The simplest way is if you have a food scale then you can measure 5 oz. If you do not have a scale then it will be one stick (8 Tbs) plus approximately 1/3 of a stick (3 Tbs). Or just measure out 11 Tbs of butter.
5.3328 tablespoons
Algebraic Steps / Dimensional Analysis Formula .3333 c*16 tablespoons
1 c=5.3328 tablespoons
There are 16 tablespoons per cup. 3 tsp to a tablespoon. The answer is 10 tablespoons plus two teaspoons, or round up to 11 tablespoons.