1lb sugar is equiv to 2.25 cups 25.5/2.25=11.33lbs
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A rough estimate would be less than 50, about 48 or so. Cups is a measure of volume. Pounds is a measure of weight and mass. You can not directly convert the two.
25 pounds is 11,350 grams. There are 250 grams in 1 cup granulated sugar, so that makes 45.4 cups.