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Episode 71 (part 2)
Oh, dude, Naruto learns the Rasen Shuriken in episode 85 of Naruto Shippuden. It's like this super cool jutsu that's all spinny and stuff. So, yeah, episode 85, check it out if you want to see Naruto spinning his way to victory.
Kakashi fights Zabuza in episodes 7-9 and then there's another battle from episodes 12-19. Hope I helped :-P
Tsunade doesn't die in Naruto Don't know about future though
The first time was episode 109, where Sasuke was just about to leave Konoha to get more power from Orochimaru because he thought he was too weak, after being defeated by the Sound Four. Sakura found him and cries that he is going to betray Konoha and offers to come with him. Sasuke refuses the offer and his final words before leaving are "Sakura, thank you for everything". He then knocks Sakura out cold and she falls to a bench.