Anton Denikin
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It is hard to say with such little information, but I believe you may be talking about "Seven Nation Army" by White Stripes.
Seven Nation Army
Stewie referred to the "Man in White" as the doctor who was present at his birth.Later in the episode after Meg joins the cult the cult leader is dressed in all white robes. He comes to the Griffin's house after Peter brings Meg back home and Stewie sees this as the man in white and he incinerates him with a laser gun.
Ghazi Abdullah Khan Achakzai, one of the first leader of the Afghan War of Independence of 1839, the first Afghan-Anglo War. Ghazi Abdullah Khan Achackzai was the national pride who regrouped the Afghan army and ordered jihad against the British army after the surrender of Amir Dost Muhammad Khan.
Pain was the former leader but now the leader is Madara.