Brooks & Dunn was the original Singer but Reba McEntire sang it with them later on.
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The actual song name is "Cry to Me," by Solomon Burke.
BETTY EVERETT SINGS THE SONG: THEY'LL COME A TIME THEY'LL COME A TIME IN EVERY GIRLS LIFE WHEN SHE'LL HAVE TO CRY CRY CRY AND THEY'LL COME A TME WHEN HER HEART WON'T TAKE MORE........ PARENTHIA GILCHRIST
It is sung by Alice Braga is called "Cry me a River", however, it's not on the soundtrack.