I believe it is Lady Tsunade the Hokage of Konoha and one of the legendary Sannin, But if you give me the exact episode and times she appears, i will tell you for sure. Example 3:59 4:10
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If your talking about 'Shippuden' Naruto. he is 16 (17 in october)
Long blonde hair, kinda skinny, and I think he has blue eyes. Here is the URL for a picture: http://www.leafninja.net/images/information/Menma.jpg
She resembles Tsunade. And orochimaru was on the same team as she was.
no but in episode 101 naruto sasuke and sakura try to get kakashi to take off his mask. spoiler alert! BEHIND THE MASK IS ANOTHER MASK. and in shippuden there was one episode where kakashi is in the hospital and you almost see his face
There is no such episode. You might be thinking of episode 101 of the original series; Gotta See! Gotta Know! Kakashi-Sensei's True Face!