That was Princess Leia, when she wore a slave outfit in the film Star Wars Episode VI: Return of the Jedi.
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Vader didn't have a bodyguard.
jawa
A nautolan. A jedi of both land and water capabilities. A "Star Wars" character.
It's not clear if you're asking which character has a bounty, or is a bounty hunter. So, if you're asking which Star Wars character has a bounty (on his head), that was Han Solo. If you're asking about a bounty hunter, there were several in the Star Wars universe. The most well known bounty hunter was Boba Fett.
Since this is a brand-new character, his name is not known yet.