Mr Burns
Smithers
Ned Flanders
Rev. Lovejoy
Kent Brockman
Dr Hibbert
Lenny
Principal Skinner
Otto
Rainier Wolfcastler
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Harry Shearer plays Ned Flanders, Rev. Lovejoy, Principal Skinner and scratchy the mouse among many others on the Simpsons. He is probably best known (at least with a cult following) as Derick Smalls in "This Is Spinal Tap". Hope that helps...
There is no pirate character on The Simpsons.You're probably referring to The Sea Captain aka Captain Horatio McCallister.
Harry Shearer
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Dan Castellaneta