Vince Gill and Carries Underwood sing the duet "How Great Thou Art." Find the video of this lovely duet on YouTube where you may be able to download it.
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The only weird name, big time duet singers of the 90's that come to mind is Peabo Bryson. In which case the African American female singer you are thinking of is Regina Belle. They did the "Alladin" duet. Again, just the first "odd" name that came to mind.
Duet
It is called a DuetDuet
A duet
Iyaz did a duet with charice on the song pyramid.