He reveals it to Sasuke after Itachi dies.
After Sasuke kills Itachi, Madara tells Sasuke about Itachi's hidden life. He also tells Sasuke who he is- Uchiha Madara! This is in Episode 140- fate.
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TOBI IS NOT OBITO BECAUSE OBITO WAS CRUSHED BY BOULDERS AND DIED AND IT IS CONFERMED IN MANGA # 40 THAT TOBI CHATS WITH PEIN(not pAin) AND KONAN AND SAYS ..." YOU GO AFTER IT AS LEADER I WILL NOT ECCEPT FAILURE" (to pein from Tobi but Tobi is hidden in shadows) AN HE SAYS " THE TRUE POWER OF THE SHARINGON ...MY POWER...UCHINE MADARA" HE SAYS HES MADARA !!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!
Madara is not Tobi.
Tobi (Madara) isn't dead yet.
Tobi , from Naruto , is voiced by Joshua Seth .
Tobi and Obito are not the same person. Tobi is Madara Uchiha. It was confirmed by himself. He will be unmasked later in the series.