In the episode The Big Bang Two, at the season finale of Season 5.
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Rory (the Roman)
Rory Williams (Amy's husband).
No, because Amy is married to Rory (or in the case of the earlier episodes, will be married to Rory).However it is clear that the Doctor had the strongest feelings for Amy than any of his previous companions.
No, Amy Dumas is not married.
Amy Bruni is not married but is expecting her first child in September 2012 with her longterm boyfriend.