Probably best to watch the whole series then the fantastic "End of Evangelion" movie.
However, be aware that many people believe the movie is meant to "replace" the last few episodes of the TV series, as they end in rather different ways.
Also, there is the re-build series of films (2 of which have already been released) which are meant to be an alternative to the timeline of the entire TV series, but they follow a similar plot to the show anyway.
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I think that you can watch it on veoh.com bt the dubing is rank so you can watch that if you want.
You can buy it from amazon.com, among other sites. Try a google shopping search. You can also go to sites like eBay.com and hope you can find an eBay vendor selling Neon Genesis Evangelion The End Of Evangelion (DVD)
Neon Genesis Evangelion OP.
Neon Genesis Evangelion's opening theme is 'Thesis of a Cruel Angel' by Yoko Takahashi whereas Mobile Suit Gundam Wing's opening theme is 'Just Communication' by TWO-MIX (eps 1-40) .
Neon Genesis Evangelion: Death & Rebirth was released first and consists of a recap and deleted scenes from the original broadcast (deleted scenes are included in renewal and platinum versions of the series) and the first half of a new plot replacing the last two episodes. Neon Genesis Evangelion: The End of Evangelion is the second movie consisting of the first half of a new plot replacing the last two episodes, which was also in Death & Rebirth and the second half of said plot, making Death & Rebirth obsolete if you have watched NGE renewal or platinum. Rebuild of Evangelion is a alternative version of the series consisting of 4 movies: 1. Evangelion: 1.0 You Are (Not) Alone 2. Evangelion: 2.0 You Can (Not) Advance 3. Evangelion: 3.0 You Can (Not) Redo 4. Evangelion: 4.0 (no official title yet)