LIFE has a total of 80 chapters.
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Currently, the Manga is still being published, and the Anime quite a bit behind the Manga. So there is no real way to tell when, or at what number the last chapter/episode will be.
Naruto shippuuden starts at chapter 245 in the Naruto Manga
Somewhere in Naruto Shippuden Manga Chapter 358-360 I think..
Shippuuden episode 111 is a filler episode. It's not in the original manga.
there isnt a manga chapter that is the same but similar things happen in a couple of chapters, but no there is not a chapter that is the same as episode 25