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The last Naruto Shippuden episode is episode 64
Over the 2 years since the last episode of naruto from naruto shippuden, within that 2 years Gaara become Kazekage of his village. Naruto becomes extremely jelous which seems to strengthen his hopes to becoming Hokage in his village Episode #2 - Naruto Shippuden (is when you find out)
The last naruto episode (not shippuden) is Naruto Episode 220
The last episode of Shippuden hasn't been aired yet
Episode 220 'Setting Off'