"Pilot".
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The first episode of Season Four. I believe it was called Charmed Again.
Leo's first appearance in Charmed was in the first season, episode 3. It's called 'thank you for not morphing.'
It's called 'Baby Not on Board' (US season 7/UK season 8)
the first episode of season 4
Yes, they do. After a few ups and downs, Chuck and Sarah finally get together properly in Series 3, Episode 13 - Chuck versus The Other Guy.