If you're referring to a catch phrase, like Bart Simpson's "Eat My Shorts" or Bugs Bunny's "What's Up Doc", Brian doesn't have one.
Although if you're referring to the word Peter claims is Brian's favorite, that would be "Bonerific"
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The song is called Surfin bird or otherwise known as "Bird is the Word"
There isn't any full length super hero episodes that I know of but in the opening sequence of the episode "FAMILY GOY" everyone is a superhero - hope that helped Family Guy Viewer Mail #1 Super Griffins segment.