There never was an episode that they went on a mission in a boat; there was a part in Movie two when Naruto, Hinata, Sakura, and there V.I.P's go on a boat.
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Answerin episode - 33
There is no first episode that Naruto and Hinata kiss because they don't kiss.
Hinata fights the Pains in episode 166 of Naruto Shippuden! it is alos the episode where she confesses her love to Naruto.
Naruto and Hinata do not make out.
i dont know the number but its called 'Hinata's confession'